25-May-2018: Ruthenium found to have unique magnetic properties at room temperature

A new experimental discovery demonstrates that the chemical element ruthenium (Ru) is the 4th single element to have unique magnetic properties at room temperature. The discovery could be used to improve sensors, devices in the computer memory and logic industry, or other devices using magnetic materials.

The use of ferromagnetism, or the basic mechanism by which certain materials (such as iron) form permanent magnets or are attracted to magnets, reaches back as far as ancient times when lodestone was used for navigation. Since then only three elements on the periodic table have been found to be ferromagnetic at room temperature -- iron (Fe), cobalt (Co), and nickel (Ni). The rare earth element gadolinium (Gd) nearly misses by only 8 degrees Celsius.

Magnetic materials are very important in industry and modern technology and have been used for fundamental studies and in many everyday applications such as sensors, electric motors, generators, hard disk media, and most recently spintronic memories. As thin film growth has improved over the past few decades, so has the ability to control the structure of crystal lattices - or even force structures that are impossible in nature. This new study demonstrates that Ru can be the fourth single element ferromagnetic material by using ultra-thin films to force the ferromagnetic phase.

The ability to manipulate and characterize matter at the atomic scale is the cornerstone of modern information technology.

Magnetic recording is still the dominant player in data storage technology, but magnetic based random-access memory and computing is beginning to take its place. These magnetic memories and logic devices put additional constraints on the magnetic materials, where data is stored and computed, compared to traditional hard disk media magnetic materials. This push for novel materials has led to renewed interest in attempts to realize predictions which show that under the right conditions, non-ferromagnetic materials, such as Ru, palladium (Pd) and osmium (Os) can become ferromagnetic.

Building upon the established theoretical predictions, researchers at the University of Minnesota used seed layer engineering to force the tetragonal phase of Ru, which prefers to have a hexagonal configuration, and observed the first instance of ferromagnetism in a single element at room temperature.

From an application perspective, Ru is interesting because it is resistant to oxidation, and additional theoretical predictions claim it has a high thermal stability - a vital requirement for scaling magnetic memories. Examination of this high thermal stability is the focus of ongoing research at the University of Minnesota.